Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2.
نویسندگان
چکیده
The mononuclear complex (Bu4N)2[ReIVCl4(CN)2]·2DMA (DMA = N,N-dimethylacetamide) displays intricate magnetization dynamics, implying Orbach, direct, and Raman-type relaxation processes. The Orbach relaxation process is characterized by an energy barrier of 39 K (27 cm-1) that is discussed based on high-field electron paramagnetic resonance (EPR), inelastic neutron scattering and frequency-domain THz EPR investigations.
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 87 شماره
صفحات -
تاریخ انتشار 2016